Home            Contact us            FAQs
    
      Journal Home      |      Aim & Scope     |     Author(s) Information      |      Editorial Board      |      MSP Download Statistics

     Research Journal of Applied Sciences, Engineering and Technology


Sintering Characteristics of Iron and Cobalt Doped Silver-tungsten Metal-matrix Composites

1Mahir Es-saheb and 2Shahid M. Azhar
1Mechanical Engineering Department
2CEREM, Advanced Manufacturing Institute, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia
Research Journal of Applied Sciences, Engineering and Technology  2014  18:3935-3947
http://dx.doi.org/10.19026/rjaset.7.752  |  © The Author(s) 2014
Received: December 19, 2013  |  Accepted: December 27, 2013  |  Published: May 10, 2014

Abstract

Silver-Tungsten composites are known as electrical contact materials used in circuit breakers and industrial relays. The performance of the contact during their service life depends upon high strength and anti-weld properties of these materials. Despite their promising industrial applications, the literature dealing with their production route is still limited. Therefore, a comprehensive study exploring the structure related properties with great emphasis on the sintering process of these materials is carried out. Therefore, in this study, the successful production of a homogeneous composite powder with controlled tungsten particle size using co-precipitation and two stage reduction techniques is followed by the compaction and sintering processes. Thus, high density compacts are produced from Fe and Co doped silver-tungsten powder using powder metallurgy technique. Various environments and sintering conditions, including N2 atmosphere and temperatures up to 1000°C, to obtain successful compacts from both doped and un-doped powders, are investigated. The morphologies and the microstructures of the sintered compacts obtained under the different sintering conditions are characterized and assessed using Scanning Electron Microscopy (SEM). Results display excellent agreement with the published studies and no evidence was found for the activated sintering of silver-tungsten by Fe additions. Also, the homogeneity of silver-tungsten in compacts is completely lost in the Fe-doped powders. However, Co additions help to facilitate the sintering between silver and tungsten whilst retaining a high homogeneity between the silver and tungsten in the sintered product.

Keywords:

Ag-W composite, co-precipitation method, electrical contacts production, metal composite, sintering,


References

  1. Albiston, J.N., 1989. Ph.D. Thesis, University of Manchester.
  2. Azhar, S.M. and M.H. Es-Saheb, 2013. Production of silver-tungsten composite with homogenous structure and controlled tungsten particle size for electrical contacts. Proceeding of 7th International Conference on Advanced Computational Engineering and Experimenting (ACE-X2013). Madrid, Spain, July 01-04.
  3. Bevington, R.C., C. Leung and P.C. Wingert, 1980. Proceeding of 26th HoIm Conference on Electrical Contacts, pp: 283-293.
  4. Bhagat, S.K., N.D. Theodore and T.L. Alford, 2008. Thermal stability of tungsten-titanium diffusion barriers for silver metallization. Thin. Solid Films, 516(21): 7451-7457.
    CrossRef    
  5. Bottelberg, P.H., E. Evert and G.H.J. Broers, 1976. Mat. Res. Bull., 11: 236.
  6. Brophy, J.H., H.W. Hayden and J. Wulff, 1962. Final stages of densification in nickel-tungsten compacts. Trans. Met. Soc. AIME, 224: 797.
  7. Bukaluk, A., M. Trzcinski and K. Okulewicz, 2008. Electron spectroscopy studies of surface In-Ag alloy formation on the tungsten surface. Appl. Surf. Sci., 254(14): 4263-4267.
    CrossRef    
  8. Carpay, E.M.A. and J. Amer, 1977. Ceram. Soc., 60: 82-83.
    CrossRef    
  9. Chaoijin, N. and R.M. German, 1983. Met. Trans. 14A: 2031.
  10. Da Costa, F.A., A.G.P. Da Silva, F.A. Filho and U.U. Gomes, 2008. Solid state sintering of a W-25 wt% Ag powder prepared by high energy milling. Int. J. Refract. Met. H., 26(4): 318-323.
    CrossRef    
  11. Es-Saheb, M.H., 2012. Porous journal bearing characteristics and performance. Proceeding of 6th International Conference on Advanced Computational Engineering and Experimenting (ACE-X2012). Istanbul, Turkey, July 01-04.
  12. Es-Saheb, M.H. and S.M. Azhar, 2013. Sintering behavior of Fe and Co doped Ag-W metal matrix composites. Proceeding of 7th International Conference on Advanced Computational Engineering and Experimenting (ACE-X2013). Madrid, Spain, July 01-04.
  13. Gáuchowski, W. and Z. Rdzawski, 2008. Thermal stability of properties in silver-rare earth metals alloys. J. Achiev. Mater. Manuf. Eng., 28(2): 143-150.
  14. German, R.M. and Z.A. Muir, 1982. Rev. Powder Met. Phys. Ceram, 2: 9-43.
  15. German, R.M., P.E. Zovas, K.S. Hwang and C.J. Li, 1983. J. Met., 35(1): 28.
  16. Gessinger, G.H. and H.F. Fischmeister, 1972. A modified model for the sintering of tungsten with Nickel additions. J. Less-Common Met., 27: 129.
    CrossRef    
  17. Gessinger, G.H., H.F. Fischmeister and H.L. Lukas, 1973. The influence of a partially wetting second phase on the sintering of solid particles. Powder Metall, 16: 119-127.
    CrossRef    
  18. Glickman, E.E., V. Bogush, A. Inberg, Y. Shacham-Diamand and N. Croitoru, 2003. Electrical resistivity of thin electro less Ag-W films for metallization. Microelectron. Eng., 70(2-4): 495-500.
    CrossRef    
  19. Hansen, M., 1958. Constitution of Binary Alloys. McGraw-Hill, New York, pp: 256.
  20. Karakas, Y., 2002. Switching performance of tungsten-silver electrical contacts. Metal Powder Report, 57(4).
    CrossRef    
  21. Kuzcynski, G.C., 1963. Powder Met., 6: 1-16.
    CrossRef    
  22. Kuzcynski, G.C. and W. Leszynki, 1961. Powder Metallurgy. Inter-Science, New York, pp: 11.
  23. Leung, C.H., R.C. Bevington, P.C. Wingert and H.J. Kim, 1982. Effects of processing methods on the contact performance parameters for Ag-W composite materials. IEEE T. Compon. Hybr., CHMT-5(1): 23-31.
    CrossRef    
  24. Özkal, B., 2002. Effects of nickel on properties of tungsten-silver electrical contact materials. Metal Powder Report, 57(7-8): 85.
    CrossRef    
  25. Paul, G.S., 2009. Effect of the electric arc and the ambient air on the contact resistance of silver, tungsten and silver-tungsten contacts. J. Appl. Phys., 47(8): 3438-3443.
    CrossRef    
  26. Ramadan, R., S.A. Ibrahi, M. Farag, A.A. Elzatahry and M.H. Es-Saheb, 2012. Processing optimization and characterization of magnetic non-oriented electrical silicon steel. Int. J. Electrochem. Sci., 7: 3242-3251.
  27. Sale, F.R. and J.N. Albiston, 1989. Powder Met.
  28. Skarsted, R.M. and S. Geler, 1975. Mat. Res. Bull., 10: 791-800.
  29. Songmei, S., W. Wenzhong, Z. Shaozhong, S. Meng and Z. Ling, 2010. Preparation of ordered mesoporous Ag/WO3 and its highly efficient degradation of acetaldehyde under visible-light irradiation. J. Hazard. Mater., 178 (1-3): 427-433.
    CrossRef    PMid:20172648    
  30. Walczuk, E., 1988. Arc erosion of silver based contacts materials in AC conditions. Proceeding of 14th International Conference on Electrical Contacts. Paris, pp: 381-385.
  31. Walden, P.J., N. Albiston and F.R. Sale, 1985. Powder Met., 20(1): 36.
    CrossRef    
  32. Walkden, P. and F.R. Sale, 1982. Proceeding of 28th Holm Conference on Electrical Contacts, pp: 101-107.
  33. Witter, G.J. and W.R. Warke, 1974. Proceeding of 20th Holm Seminar, pp: 78.
  34. Witter, G. and W. Warke, 1975. IEEE T. P.H.P., 11: 21-29.

Competing interests

The authors have no competing interests.

Open Access Policy

This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

Copyright

The authors have no competing interests.

ISSN (Online):  2040-7467
ISSN (Print):   2040-7459
Submit Manuscript
   Information
   Sales & Services
Home   |  Contact us   |  About us   |  Privacy Policy
Copyright © 2024. MAXWELL Scientific Publication Corp., All rights reserved