Research Article | OPEN ACCESS
Measurement of Available Phosphorus and Potassium Contents in Soil using Visible-near-infrared Spectroscopy in Conjunction with SPA-LS-SVM Methods
Zhang Lei and Zhang Rong-Biao
School of Electric Information Engineering, Jiangsu University, Zhenjiang 212013, China
Advance Journal of Food Science and Technology 2016 12:934-941
Received: May 30, 2015 | Accepted: August 5, 2015 | Published: April 25, 2016
Abstract
Applying Near Infrared Reflectance Spectroscopy (NIRS) on farmlands can effectively estimate the available phosphorus and potassium contents of soil online. Spectral preprocessing, including Savitzky Golay (SG), Standard Normal Variate (SNV), Multiplicative Scatter Correction (MSC) and SG 1st derivative, aimed to eliminate system noise and external interference. A correction model was created using respectively Radial Basis Function (RBF) and Least Squares Support Vector Machine (LS-SVM) methods with input from the characteristic wavelengths obtained using Successive Projections Algorithm (SPA). The results of predicting available phosphorus and potassium contents in soil using these two modeling methods were evaluated and the better model was selected. The results showed that the LS-SVM method with input from the characteristic wavelengths obtained using SPA had an advantage over the RBF modeling method. In SPA-LS-SVM models, the correlation coefficient and mean square error of prediction for available phosphorus were 0.8625 and 8.67 and those for available potassium were 0.7843 and 13.42, respectively. This indicates that SPA-based visible-near-infrared spectroscopy using LS-SVM for modeling can be used as a method to accurately measure available phosphorus and potassium contents in soil.
Keywords:
LS-SVM, RBF, Spectroscopy, SPA,
References
-
Bao, Y., Y. He, H. Fang and A.G. Pereira, 2007. Spectral characterization and N content prediction of soil with different particle size and moisture content. Spectrosc. Spect. Anal., 27(1): 62-65.
-
Barthes, B.G., D. Brunet, E. Hien, F. Enjalric, S. Conche, G.T. Freschet, R. d’Annunzio and J. Toucet-Louri, 2008. Determining the distributions of soil carbon and nitrogen in particle size fractions using near-infrared reflectance spectrum of bulk soil samples. Soil Biol. Biochem., 40: 1533-1537.
CrossRef -
Bogrekci, I. and W.S. Lee, 2005a. Spectral soil signatures and sensing phosphorus. Biosyst. Eng., 92(4): 527-533.
CrossRef -
Bogrekci, I. and W.S. Lee, 2005b. Improving phosphorus sensing by eliminating soil particle size effect in spectral measurement. T. ASABE, 48(5): 1971-1978.
CrossRef -
Bogrekci, I. and W.S. Lee, 2006. Effects of soil moisture content on absorbance spectra of sandy soils in sensing phosphorus concentrations using UV-VIS-NIR spectroscopy. T. ASABE, 49(4): 1175-1180.
CrossRef -
Brichlemyer, R. and D. Brown, 2010. On-the-go VisNIR: Potential and limitations for mapping soil clay and organic carbon. Comput. Electron. Agric. 70(2): 209-216.
CrossRef -
Chen, B., G. Liu and X.M. Zhang, 2013. Analysis on near infrared spectroscopy of water content in lubricating oil using successive projections algorithm. Infrared Laser Eng., 42(12): 3168-3174.
-
Confalonieri, M., F. Fornasier, A. Ursino, F. Boccardi, B. Pintus and M. Odoardi, 2001. The potential of near infrared reflectance spectroscopy as a tool for the chemical characterisation of agricultural soils. J. Near Infrared Spec., 9(2): 123-131.
CrossRef -
Gomez, C., R.A. Viscarra Rossel and A.B. McBratney, 2008. Soil organic carbon prediction by hyperspectral remote sensing and field vis-NIR spectroscopy: An Australian case study. Geoderma, 146(3-4): 403-411.
CrossRef -
Li, W., S.H. Zhang, Q. Zhang et al., 2007. Rapid prediction of available N,P and K content in soil using near-infrared reflectance spectroscopy. T. Chinese Soc. Agric. Eng., 23(1): 55-59.
-
Minasny, B., A.B. McBratney, V. Bellon-Maurel, J. Roger, A. Gobrecht, L. Ferrand and S. Joalland, 2011. Removing the effect of soil moisture from NIR diffuse reflectance spectra for the prediction of soil organic carbon. Geoderma, 167: 118-124.
CrossRef -
Mouazen, A.M., J. De Baerdemaeker and H. Ramon, 2005. Towards development of online soil moisture content sensor using a fibre-type NIR spectrophotometer. Soil Till. Res., 80: 171-183.
CrossRef -
Mouazen, A.M., R. Karoui, J. De Baerdemaeker and H. Ramon, 2006. Characterization of soil water content using measured visible and near infrared spectra. Soil Sci. Soc. Am. J., 70(4): 1295-1302.
CrossRef -
Pan, L., J. Wang, P. Li, Q. Sun, Y. Zhang and D. Han, 2009. Region optimization of SSC model for pyrus pyrifolia by genetic algorithm. Spectrosc. Spect. Anal., 29(05): 1246-1250.
-
Reeves III, J.B. and D.B. Smith, 2009. The potential of mid-and near-infrared diffuse reflectance spectroscopy for determining major-and trace-element concentrations in soils from a geochemical survey of North America. Appl. Geochem., 24(8): 1472-1481.
CrossRef -
Reeves III, J.B., 2010. Near- versus mid-infrared diffuse reflectance spectroscopy for soil analysis emphasizing carbon and laboratory versus on-site analysis: where are we and what needs to be done? Geoderma, 158(1-2): 3-14.
CrossRef -
Rossel, R.A.V., D.J.J. Walvoort, A.B. McBratney, L.J. Janik and J.O. Skjemstad, 2006. Visible, near infrared, mid infrared or combined diffuse reflectance spectroscopy for simultaneous assessment of various soil properties. Geoderma, 131(1-2): 59-75.
CrossRef -
Sun, T., W.L. Xu, J.L. Lin, M.H. Liu and X.W. He, 2012. Determination of soluble solids content in navel orange by Vis/NIR diffuse transmission spectra combined with CARS method. Spectrosc. Spect. Anal., 32(12): 3229-3233.
-
Wang, H., C. Li and M. Wang, 2013. Quantitative determination of onion internal quality using reflectance, interactance and transmittance modes of hyperspectral image. T. ASABE, 56(4): 1623-1635.
-
Wang, M., X. Xie, R. Zhou et al., 2011. Determination of soil organic matter in red soils using VIS-NIR diffuse reflectance spectroscopy selection of optimal spectral bands. Acta Pedol. Sinica, 48(5): 1083-1089.
-
Yu, Y., 2011. Quantitative determination of parameters of substrate using near-infrared spectroscopy technique. Spectrosc. Spect. Anal., 31(11): 2928-2931.
Competing interests
The authors have no competing interests.
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This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
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