Research Article | OPEN ACCESS
Kinetic and Equilibrium Studies for the Removal of Bromate by the Modified Activated Carbon
1Muqing Qiu and 2Shuiying Xiong
1College of Life Science, Shaoxing University
2Department of Life Science, Shaoxing University Yuanpei College, Shaoxing, 312000, P.R. China
Advance Journal of Food Science and Technology 2015 7:548-552
Received: November 7, 2014 | Accepted: December 18, 2014 | Published: March 05, 2015
Abstract
Bromate which was formed bromide dissolved in water during the ozonation process, is carcinogenic and mutagenic to humans. To avoid bromate damage, many countries strictly control its concentration in drinking water. Activated carbon is an effective adsorbent material widely used in water treatment. In order to enhance the adsorption of bromate ion on activated carbon, the modified activated carbon was obtained from granular activated carbon by chemical activation using cationic surfactant as an activator. The adsorption characteristics of bromate ion on the modified activated carbon were investigated through adsorption experiments. The effects of temperature, pH in solution, contact time and initial bromate concentration on bromate adsorption by the modified activated carbon were investigated. The experimental data were analyzed by the Langmuir and Freundlich models of adsorption. Kinetic adsorption data were analyzed by the pseudo-first-order kinetic model and the pseudo-second-order model, respectively.
Keywords:
Activated carbon, adsorption, bromate, equilibrium, kinetic,
References
-
Bhatnagar, A., Y.H. Choi and Y.J. Yoon, 2009. Bromate removal from water by granular ferric hydroxide. J. Hazard. Mater., 170: 134-140.
CrossRef PMid:19481866 -
Chen, W.F., Z.Y. Zhang, Q. Li and H.Y. Wang, 2012. Adsorption of bromate and competition from oxyanions on cationic surfactant-modified granular activated carbon. Chem. Eng. J., 203: 319-325.
CrossRef -
Chitrakar, R., A. Sonoda, Y. Makia and T. Hirotsu, 2011. Calcined Mg-Al layered double hydroxides for uptake of trace levels of bromate from aqueous solution. Ind. Eng. Chem. Res., 50: 9280-9285.
CrossRef -
Ding, L.A., Q. Li, H. Cui, R. Tang, H. Xu, X.C. Xie and J.P. Zhai, 2010. Electrocatalytic reduction of bromate ion using a polyaniline-modified electrode: An efficient and green technology for the removal of BrO3- in aqueous solutions. Electrochim. Acta, 55: 8471-8475.
CrossRef -
Freundlich, H.M.F., 1906. Over the adsorption in solution. J. Phys. Chem., 57: 385-470.
-
Gong, C.H., Z.G. Zhang, Q.L. Qian, D. Liu, Y.J. Cheng and G.Q. Yuan, 2013. Removal of bromide from water by adsorption on silver-loaded porous carbon spheres to prevent bromate formation. Chem. Eng. J., 218: 333-340.
CrossRef -
Ho, Y.S. and G. Mckay, 1998. Kinetic models for the sorption of dye from aqueous solution by wood. Trans. Inst. Chem. Eng. B, 76: 183-191.
CrossRef Direct Link -
Huang, W.J. and Y.L. Cheng, 2008. Effect of characteristics of activated carbon on removal of bromate. Sep. Surf. Technol., 59: 101-107.
CrossRef -
Langmuir, I., 1918. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc., 40: 1361-1403.
CrossRef -
Li, J. and J.C. Wang, 2011. Complex kinetics and significant influences of bromine removal in ferroin-bromate-metol reaction. Phys. Chem. Chem. Phys., 13: 15539-15545.
CrossRef PMid:21808799 -
Li, H., G. Huang, C. An, J. Hu and S. Yang, 2013. Removal of tannin from aqueous solution by adsorption onto treated coal fly ash: Kinetic, equilibrium, and thermodynamic studies. Ind. Eng. Chem. Res., 52: 15923-15931.
CrossRef -
Listiarini, K., J.T. Tor, D.D. Sun and J.O. Leckie, 2010. Hybrid coagulation-nanofiltration membrane for removal of bromate and humic acid in water. J. Membrane Sci., 365: 154-159.
CrossRef -
Marhaba, T.F. and K. Bengranie, 2003. Review of strategies for minimizing bromate formation resulting from drinking water ozonation. Clean. Technol. Envir., 5: 101-112.
CrossRef -
Moslemi, M., S.H. Davies and S.J. Masten, 2012. Empirical modeling of bromate formation during drinking water treatment using hybrid ozonation membrane filtration. Desalination, 292: 113-118.
CrossRef -
Patterson, J., R. Parette, F.S. Cannon, C. Lutes and T. Henderson, 2011. Competition of anions with perchlorate for exchange sites on cationic surfactant-tailored GAC. Environ. Eng. Sci., 28: 249-256.
CrossRef -
Thinakaran, N., P. Panneerselvam, P. Baskaralingam, D. Elango and S. Sivanesan, 2008. Equilibrium and kinetic studies on the removal of acid red 114 from aqueous solutions using activated carbons prepared from seed shells. J. Hazard. Mater., 158: 142-150.
CrossRef PMid:18313841 -
Tsubouchi, M., H. Mitsushio and N. Yamasaki, 1981. Determination of cationic surfactants by two-phase titration. Anal. Chem., 53: 1957-1959.
CrossRef -
Wang, L., J. Zhang, J.Z. Liu, H. He, M. Yang, J.W. Yu, Z.C. Ma and F. Jiang, 2010. Removal of bromate ion using powdered activated carbon. J. Environ. Sci., 22: 1846-1853.
CrossRef -
Wolf, D.C., L.M. Crosby, M.H. George, S.R. Kilburn, T.M. Moore, R.T. Miller and A.B. Deangelo, 1998. Time and dose dependent development of potassium bromate induced tumors in male Fischer 344 rats. Toxicol. Pathol., 26: 724-729.
CrossRef PMid:9864088
Competing interests
The authors have no competing interests.
Open Access Policy
This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Copyright
The authors have no competing interests.
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