Research Article | OPEN ACCESS
Gas Permeability and Selectivity of Synthesized Diethanol Amine-Polysulfone/Polyvinylacetate Blend Membranes
Asim Mushtaq, Hilmi Mukhtar and Azmi Mohd Shariff
Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh 31750, Perak, Malaysia
Research Journal of Applied Sciences, Engineering and Technology 2014 5:600-605
Received: March ‎29, ‎2014 | Accepted: April ‎28, ‎2014 | Published: August 05, 2014
Abstract
The control of anthropogenic carbon dioxide release is one of the most challenging environmental problem faced by developing countries, as the interfering of atmospheric carbon dioxide level and climate revolutionize. An rising technology is the membrane gas separation, which is more dense, energy efficient and possibly more economical than past technologies, such as solvent absorption. Amine has a greater efficiency for removal of carbon dioxide. The blending technique not only provides improved chemical and thermal stability but is also efficient enough to improve the perm-selective properties with economical viability. In this study, research will be carried out to study the gas permeability behavior of glassy Polysulfone and Polyvinyl acetate rubbery polymeric blend membranes with diethanol amine. Polymeric amine blend membranes with different blending ratios were prepared in dimethyl acetamide solvent, flat sheet membrane were developed with enhance properties. We were studied PSU/PVAc blend with DEA amine using a gas permeability application for CO2 and CH4 at different feed pressures.
Keywords:
Blend membrane , carbon dioxide removal, DEA amine , gas permeability , natural gas , PSU polymer,
References
-
Al-Masri, M., H.R. Kricheldorf and D. Fritsch, 1999. New polyimides for gas separation. 1. Polyimides derived from substituted terphenylenes and 4,4 '- (hexafluoroisopropylidene)diphthalic anhydride. Macromolecules, 32: 7853.
CrossRef -
Baker, R.W., 2004. Membrane Technology and Applications. 2nd Edn., John Wiley and Sons, ISBN 0-470-85445-6, West Sussex.
CrossRef
-
Barbari, T.A., W.J. Koros and D.R. Paul, 1988. Gas transport in polymers based on bisphenol-A. J. Polym. Sci. Pol. Phys., 26(4): 709-727.
CrossRef -
Bikson, B., M.J. Coplan and G. Goetz, 1985. Compositions and method of preparation by chlorosulfonation of dif?cltly sulfonatable poly(ethersulfone). US Patent, US4508852.
-
Blauwhoff, P.M.M., G.F. Versteeg and W.P.M. van Swaaij, 1984. A study of the reaction between CO2 and alkanolamines in aqueous solutions. Chem. Eng. Sci., 39: 207-225.
CrossRef
-
Bourganel, J., 1977. US4026977 (1977).
-
Budd, P.M., K.J. Msayib, C.E. Tattershall, B.S. Ghanem, K.J. Reynolds, N.B. McKeown and D. Fritsch, 2005. Gas separation membranes from polymers with intrinsic microporosity. J. Membrane Sci., 251(1-2): 263-369.
CrossRef
-
Chiao, C.C., 1988. US4717395.
-
Chiao, C.C., 1989. US4828585.
-
Coplan, M.J., C.H. Park and S.C. Williams, 1983. US4414368 (1983).
-
Glasscock, D.A., J.E. Critchfield and R.T. Rochelle, 1991. CO2 absorption/desorption in mixtures of methyldiethanolamine with monoethanolamine or diethanolamine. Chem. Eng. Sci., 46: 2829-2845.
CrossRef -
Graefe, A.F., C.W.J. Saltonstall and W.J. Schell, 1975. US3875096.
-
Hachisuka, H., T. Ohara, K.I. Ikeda and K. Matsumoto, 1995. Gas permeation property of polyaniline films. J. Appl. Polym. Sci., 56(11): 1479-1485.
CrossRef
-
Houde, A.Y., S.S. Kulkerni and M.G. Kulkerni, 1992. Permeation and plasticization behavior of glassy polymers: A WAXD interpretation. J. Membrane Sci., 71(1-2): 117-128.
CrossRef
-
Kawakami, J.H., B. Bikson, G. Gotz and Y. Ozcayir, 1991. EP0426118 (1991).
-
Kerry, F.G., 2007. Industrial Gas Handbook: Gas Separation and Purification, CRC, New York, ISBN 978-0- 8493-9005-0.
CrossRef -
Kroschwitz, J.I., 1989. Encyclopedia of Polymer Science and Engg. John Wiley, New York, Vol. 17.
-
Lin, W.H. and T.S. Chung, 2001. Gas permeability, diffusivity, solubility and aging characteristics of 6FDA-durene polyimide membranes. J. Membrane Sci., 186(2): 183-193.
CrossRef -
Littel, R.J., G.F. Versteeg and W.P.M. van Swaaij, 1992. Kinetics of CO2 with primary and secondary amines in aqueous solutions, influence of temperature on zwitterion formation and deprotonation rates. Chem. Eng. Sci., 47: 2037-2045.
CrossRef -
Mizumoto, T., T. Masuda and T. Higashimura, 1993. Polymerization of [o- (trimethylgermyl) phenyl] acetylene and polymer characterization. J. Polym. Sci. Pol. Chem., 31(10): 2555-2561.
CrossRef -
Nagel, C., K.G. Unther-Schade, D. Fritsch, T. Strunskus and F. Faupel, 2002. Free volume and transport properties in highly selective polymer membranes. Macromolecules, 35(6): 2071-2077.
CrossRef -
Quentin, J., 1973. US3709841.
-
Quentin, J., 1977. US4054707.
-
Rose, J.B., 1981a. US4268650.
-
Rose, J.B., 1981b. US4273903.
-
Shida, Y., T. Sakaguchi, M. Shiotsuki, F. Sanda, B.D. Freeman and T. Masuda, 2006. Synthesis and properties of membranes of poly (diphenylacetylenes) having fluorines and hydroxyl groups. Macromolecules, 39(2): 569-574.
CrossRef
-
Versteeg, G.F. and M.H. Oyevaar, 1989. The reaction of CO2 and diethanolamine at 298K. Chem. Eng. Sci., 44: 1264-1268.
CrossRef
-
Versteeg, G.F. and W.P.M. van Swaaij, 1988. Solubility and diffusivity of acid gases (CO2, N2O) in aqueous alkanolamine solutions. J. Chem. Eng. Data, 33: 29-34.
CrossRef -
Versteeg, G.F., J.A.M. Kuipers, F.P.H. van Beckum and W.P.M. van Swaaij, 1990. Mass transfer with complex reversible Chemical reactions-II. parallel reversible chemical reactions. Chem. Eng. Sci., 45: 183-197.
CrossRef
-
Wang, L., Y. Cao, M. Zhou, S.J. Zhou and Q. Yuan, 2007. Novel copolyimide membranes for gas separation. J. Membrane Sci., 305: 338-346.
CrossRef -
Yang, L., J. Fang, N. Meichin, K. Tanaka, H. Kita and K. Okamoto, 2001. Gas permeation properties of thianthrene-5, 5, 10, 10-tetraoxide-containing polyimides, Polymer, 42: 2021-2029.
CrossRef
-
Zimmerman, C.M. and W.J. Koros, 1999. Polypyrrolones for membrane gas separations. I. Structural comparison of gas transport and sorption properties. J. Polym. Sci. Pol. Phys., 37: 1235-1249.
CrossRef
Competing interests
The authors have no competing interests.
Open Access Policy
This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Copyright
The authors have no competing interests.
|
|
|
ISSN (Online): 2040-7467
ISSN (Print): 2040-7459 |
|
Information |
|
|
|
Sales & Services |
|
|
|